Monday, December 3, 2018

A skeptical chemist’s view of global warming



Vincent J. Curtis

28 Nov 2018

I propose to set forth my objections to the fear-monger surrounding the issue of run-away global warming.

The most important factor in the warming of the earth is the energy output of the sun.  If the sun went dark, it would not take long for the earth to assume a temperature approximating that of outer space.  The sun is where all the heat comes from. The difference between summer and winter and between day and night serve as examples of the power of the sun.  We can call the energy output of the sun the first order factor of the temperature of the earth’s atmosphere.

 All the anthropogenic global warming hypotheses assume that the energy output of the sun is absolutely constant.  This is a radical and unwarranted assumption.  The earth has experienced several ice ages, and periods of great warmth, as when the dinosaurs roamed the planet.  In the 20th century alone, the 1930s were a period of extraordinary heat, and the earth’s temperature cooled between 1940 and 1970 – setting off a ‘coming ice age’ scare.  None of these things had anything to do with man or carbon dioxide.  The sun is the first order factor of the earth’s atmospheric temperature, and all second and higher order factors react to it.

Let’s assume for the moment that absolute constancy holds, at least for brief periods of time.  We look then at the second and third order factors that affect global atmospheric temperature  .If the assumption that global temperatures are affected by atmospheric carbon dioxide is true, what can we expect as carbon dioxide increased in concentration? As a first approximation, we would expect global average temperature to increase linearly as follows: ΔT = mΔC, where ΔT is the increase in temperature, ΔC is the increase in carbon dioxide concentration, and m is the rate of increase.  With all other factors being held constant we should expect to see a consistent, linear increase in temperature with increase in carbon dioxide.  But we are not seeing anything like that, and so all other factors cannot be constant.  Factors other than carbon dioxide must also be playing a role – a more important role - in increasing global temperatures.

Let’s look at another factor.  The ideal gas law is as follows: PV=nRT, where P is pressure, V is volume, n is the quantity of gas, T is absolute temperature, and R is a constant.  Since n, the quantity of the atmosphere, is constant, and atmospheric pressure is constant, any increase in temperature would result in an expansion of the volume of the atmosphere.  The atmosphere consists of nitrogen to the extent of 78 percent, and nitrogen is subject to the Joule-Thompson effect.  This means that an adiabatic expansion of a volume of nitrogen will result in a decrease in temperature of the gas.  Anyone who has cracked open a cylinder of compressed nitrogen will have seen the valve and outlet of the cylinder get covered in frost - this is the Joule-Thompson effect in action.  Any expansion of the earth’s atmosphere due to an increase in temperature would see an offsetting response as a result of that expansion.  Since nitrogen comprises 78 percent of the earth’s atmosphere while carbon dioxide comprises only 0.04 percent, the moderating effect of nitrogen is extremely powerful as compared to a heating effect of carbon dioxide.

The atmosphere of Venus consists of 96 percent carbon dioxide.  Any likening of the earth turning into a Venus fails to observe the large differences in compositions between the two atmospheres.  In addition, Venus has about thirty times the amount of atmosphere that earth does.  Where Venus has atmosphere, earth has oceans, and the oceans have a far greater capacity to absorb heat and moderate temperature than the earth’s atmosphere does.  The earth is nothing like Venus, and the earth’s atmosphere can’t experience run-away temperatures without a dramatic change in solar output.

Carbon dioxide is ominously referred to as a “greenhouse gas,” and people who make this observation don’t seem to know much about greenhouses.  Carbon dioxide is added to a greenhouse to increase the bulk of the plants, not to heat the place.  Plants use carbon dioxide in photosynthesis to grow and develop; more CO2, bigger plants.  The heat felt in greenhouses is produced by the glass, not the gas.

My old university residence had common rooms that used to get very hot on the coldest of winter days under a bright winter sun.  Ordinary window glass traps most infra-red radiation, and the bright sun shining on the dark carpet and furniture of the common room produced a lot of infra-red radiation.  The trapping of heat in a greenhouse relies on plain window glass being opaque to most infra-red radiation.  Greenhouses work by trapping infra-red radiation with ordinary window glass, not with carbon dioxide, which absorbs at a specific frequency of infra-red.

To recap to this point: the sun is where all the heat comes from.  The oceans are the great second order moderator of heat on earth’s surface, due to their capacity both to absorb heat from and release heat and moisture to the atmosphere.  The third order moderator is the atmosphere itself, being composed largely of nitrogen and not being all that massive, especially as compared to the oceans.

The greatest variable in atmospheric composition is humidity, and water vapor absorbs at specific frequencies in the infra-red region as carbon dioxide does.  Carbon dioxide is a minor constituent.  To the extent that carbon dioxide absorbs (and emits) infra-red radiation at a specific frequency, the global warming hypothesis requires a linear increase in atmospheric temperature, neglecting the moderating effect of nitrogen, and holding all other factors constant.  But we aren’t seeing simple, linear increases with ΔC.  Other factors must, therefore, be playing roles, and those factors are all more powerful in their effects than carbon dioxide.

Significant, prolonged changes in global temperatures must be due to natural variation in the first order – the sun.  Smaller changes of shorter duration can be due to changes in the second order – the oceans.  In the third order, nitrogen, by absorbing or releasing heat when expanding or contracting, tends to offset the effects of small changes in the first and second orders. (Another example of Le Chatelier’s principle in action, and explains why small changes do not result in run-away outcomes.)

Like water vapor, carbon dioxide doesn’t just absorb infer-red radiation – it releases it too.  At best, the potential effect of carbon dioxide is to delay, but not prevent, the release of heat to outer space, and is too small and too easily offset by nitrogen, and by the oceans to be that consequential.

To this scientist, the experts who speak most fearfully of run-away global warming are making unwarranted assumptions about all the important factors, the first being solar output.  They exhibit no understanding of how a greenhouse works.  They exhibit no knowledge of the thermodynamics of real gases, or heat capacities.  They don’t seem to understand the establishment of a new equilibrium.  Their fears of run-away temperatures confirm to me their lack of important knowledge.  They simply ignore (or worse – cover up) the failings of their theory.

Finally, they are unscientific.  A time versus temperature graph does not establish a cause-effect relationship between time and temperature, or anything else.

On the other hand, the politics of global warming are obvious and satisfying to many, especially on the left.  A lot of people have made good money playing prophets of doom.  The sheer politicization of what should be a scientific curiosity indicates to me that politics is the predominant factor in all the fearmongering.  The stench of politics hangs over climate science like a sign of something rotten.

I hope this article serves as an antidote to fears of man-caused run-away global warming.
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Vincent J. Curtis is a Canadian research scientist and occasional free-lance writer.



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